Well, technically speaking, silicone is silicone, so caulk will eventually set.
But as the man said, 'ya get what you paid fer.'
I shudder when I see guys pouring resin like that (plaster was way too thin as well, it'll disintegrate into chalk over time like that). Eyeballing hardeners makes me chuckle, but during the hardening phase, most resins shed some nasty isocyanates that'll shut down your lungs pretty quick. Not the lightheadedness you may get with solvents, but they literally bond with any water anywhere to form a crust. Could be on a glass of water (I have a friend whose aquarium was destroyed after a spill), but most likely on your moist lung surfaces if your head is right over it. And there's no respirator that filters the stuff either. If you do it, please be smart about it.